They are called The Dear Hunter, and the solo at 20:43 will melt your face.
If you like bands like jack's mannequin or say anything, maybe even dashboard confessional a little bit, you will like these guys, the singer is absolutely amazing. Keep in mind this is lief, non live versions of there songs are probably better but they are still good.
My sisters boyfriend did sound for them at a show once and that's how i found out about them, the singer has one of the most amazing voices ever.